- Effect of Solution Properties on Luminance Characteristics of YAG:Ce Phosphors Prepared by Spray Pyrolysis
-
You-Mi Lee, Tae-Won Kang, Kyeong-Youl Jung
-
J Korean Powder Metall Inst. 2012;19(3):220-225.
-
DOI: https://doi.org/10.4150/KPMI.2012.19.3.220
-
-
 Abstract
 PDF
- YAG:Ce yellow phosphor particles were synthesized by spray pyrolysis with changing the solution properties and their luminous properties, crystal structure, and morphological changes were studied by using PL measurement, XRD, and SEM analysis. It was clear that the solution properties significantly affected the crystal phase, crystallite size, the PL intensity, and the morphology of YAG:Ce particles. At low calcination temperature, the addition of urea only to the spray solution was helpful to form a pure YAG phase without any impurity phases, as the result, the highest luminescence intensity was achieved at the calcination temperature of 900°C. When the calcination temperatures were larger than 1300°C, however, the YAG particles prepared without any additive showed the highest luminescent intensity. Regardless of the solution conditions, the emission intensity of YAG:Ce particles prepared by spray pyrolysis showed a linear relation with the crystallite size. In terms of the morphology of YAG:Ce particles, the addition of both DCCA and NH_4OH to the spray solution was effective to prepare a spherical and dense structured YAG particles.
|
kpmi
